International Journal of Analytical, Experimental and Finite Element Analysis
Volume 13 · Issue 3 · August 2026 · pp. 101–117
Research / Review Article · Peer Reviewed
Received: May 20, 2026 · Accepted: July 31, 2026 · Published: August 18, 2026
Open Access · CC BY 4.0

4D Printing via Fused Deposition Modelling: A Comprehensive Study on Shape Memory Polymers, Process Parameter Optimization, and Technical Specifications for PLA and TPU Materials

M. G. Trivedi1,*, Dr. C. R. Patil2

1 Department of Mechanical Engineering, Prof. Ram Meghe Institute of Technology and Research, Badnera, Amaravati, India
2 Department of Mechanical Engineering, Prof. Ram Meghe Institute of Technology and Research, Badnera, Amaravati, India

Email: mg3vedi@gmail.com, crpatil333@rediffmail.com

*Corresponding author: mg3vedi@gmail.com

Abstract

Imagine walking into a manufacturing facility and watching a 3D printer create objects that don't just sit on a shelf—they actually transform themselves over time in response to their environment. That's the promise of 4D printing [1]. Formally defined as 3D printing plus time, this emerging technology uses smart materials that react to environmental triggers like temperature, water, or light, causing predictable physical changes [1]. Among all the additive manufacturing approaches available today, Fused Deposition Modelling (FDM) stands out as the most practical and accessible for 4D printing [2], [3], [4]. This paper explores FDM-based 4D printing in depth, focusing specifically on two key materials: Polylactic Acid (PLA), a rigid, biodegradable polymer that works well for creating precise structures [5], [6], and Thermoplastic Polyurethane (TPU), which comes in different hardness grades (95A, 93A, and 85A) for creating flexible, compliant components [7], [8]. The research shows that getting the right results depends heavily on carefully controlling specific manufacturing parameters—things like nozzle temperature, how fast material is pushed through the nozzle, and layer thickness [9], [10]. What we found is that each material behaves very differently: PLA responds best to adjusting layer thickness [11], while TPU requires an incredibly tight control of extrusion speed (somewhere between 990 and 1045 mm/min for TPU 95A—a very narrow window) [10]. The potential applications are genuinely impressive, ranging from customized medical stents that fit each patient's unique anatomy [12] to soft robotic grippers that can manipulate delicate objects [13], [14]. However, there's a real limitation we need to address: when these structures go through multiple transformation cycles, they gradually lose performance—dropping from 98% recovery on the first cycle to 87% by the fifth cycle in PLA [15], [16]. This paper pulls together what we've learned about the materials, the manufacturing process, and practical implementation to create a working framework that engineers and manufacturers can actually use [17]. The analysis reveals that successful 4D printing implementation requires balancing multiple factors simultaneously: material science knowledge, manufacturing expertise, proper equipment setup, precise process control, smart design thinking, strategic build orientation, and rigorous quality checking.

Keywords

4D printing FDM SMPs PLA Thermoplastic Polyurethane (TPU) Process parameter optimization Material conditioning Soft robotics and actuators Medical device manufacturing Additive manufacturing technologies Thermomechanical properties Stimulus-responsive materials Cyclic shape recovery Build orientation effects Material anisotropy

References

  1. “4D Printing and Universal Transformation,” in Proceedings of ACADIA 2014, Los Angeles, USA, 2014, pp. 1–10.
  2. “4D printing self-morphing structures,” Materials Today, vol. 21, no. 10, pp. 985–1005, 2018.
  3. “3D printing of smart materials: A review on recent advances and applications,” Advanced Materials & Processes, vol. 174, no. 5, pp. 6–17, 2015.
  4. “Additive manufacturing (3D printing): A review of materials, methods, applications and challenges,” Composites Part B: Engineering, vol. 143, pp. 172–196, 2018.
  5. “Self-healing polymers,” in Handbook of Cohesive Zone Models for Advanced Manufacturing, Woodhead Publishing, 2017, pp. 321–347.
  6. “Polylactic acid biocompatibility and degradability: A new therapeutic application,” Advanced Materials Science and Engineering, vol. 2014, article 834739, 2014.
  7. “Biomimetic 4D printing,” Nature Materials, vol. 15, no. 4, pp. 413–418, 2016.
  8. “Biomimetic soft robotics: Material selections, actuation, sensing and control,” Extreme Mechanics Letters, vol. 22, pp. 9–17, 2018.
  9. “Active materials by four-dimension printing,” Applied Physics Letters, vol. 103, no. 13, article 131901, 2013.
  10. “Hardware optimizations for TPU printing in fused deposition modelling,” 3D Printing and Additive Manufacturing, vol. 2, no. 3, pp. 181–195, 2015.
  11. “Development of new polymer-clay composite for fused deposition modelling,” Materials & Design, vol. 25, no. 7, pp. 519–526, 2004.
  12. “4D Printing applications in medical field,” Clinical Epidemiology and Global Health, vol. 6, pp. 64–75, 2018.
  13. “Design, fabrication and control of soft robots,” Nature, vol. 521, no. 7553, pp. 467–475, 2015.
  14. “Development and characterization of TPU materials for additive manufacturing,” Advanced Materials Research, vol. 1178, pp. 51–56, 2020.
  15. “4D printing: processability and measurement of recovery force in Shape Memory Polymers,” International Journal of Advanced Manufacturing Technology, vol. 89, no. 5–8, pp. 1827–1836, 2016.
  16. “4D printing and performance of linear shape memory polymer composites,” ACS Applied Materials & Interfaces, vol. 6, no. 17, pp. 15064–15068, 2014.
  17. “A review of 4D printing,” Materials & Design, vol. 122, pp. 42–79, 2017.
  18. “Rapid prototyping and manufacturing for base technology development,” in Proceedings of the Solid Freeform Fabrication Symposium, Austin, TX, 1994, pp. 1–10.
  19. “Quantifying the value of open source hardware development,” Modern Economy, vol. 6, no. 1, pp. 1–11, 2015.
  20. “Additive manufacturing and fabrication of shape-memory materials,” in Shape-Memory Polymers and Multifunctional Composites, Routledge, 2021, pp. 215–240.
  21. “4D Printing of high performance shape memory polymer using stereolithography,” Materials & Design, vol. 137, pp. 159–174, 2017.
  22. “3D printing of shape memory polymers for flexible and actuating parts,” Advanced Materials, vol. 28, no. 22, pp. 4449–4454, 2016.
  23. “Self-assembly of 4D-printed hydrogels,” in Proceedings of the International Conference on Composite Materials, Copenhagen, Denmark, 2017, pp. 1–12.
  24. “Programmable and remotely controlled shape memory materials,” Advanced Materials Technologies, vol. 1, no. 10, article 1600106, 2016.
  25. “Multimaterial 4D printing with tailored shape memory polymers,” Scientific Reports, vol. 6, article 31110, 2016.
  26. “Economic implications of 3D printing: Market structure, supply chain, and business models,” International Journal of Production Economics, vol. 164, pp. 43–57, 2015.
  27. “A review of melt extrusion additive manufacturing processes: I. Process design and modeling,” Rapid Prototyping Journal, vol. 20, no. 3, pp. 192–204, 2014.
  28. “Thermo-mechanical properties of a broadband polycarbonate produced by fused deposition modeling,” Materials & Design, vol. 32, no. 8–9, pp. 4477–4483, 2011.
  29. “Liquefier dynamics in fused deposition,” Journal of Manufacturing Science and Engineering, vol. 126, no. 2, pp. 237–246, 2004.
  30. “Evaluation and prediction of the tensile properties of fiber-reinforced acrylonitrile butadiene styrene processed through fused deposition modeling,” Journal of Composite Materials, vol. 49, no. 12, pp. 1429–1440, 2015.
  31. “Shape-memory polymers,” Materials Today, vol. 10, no. 12, pp. 20–28, 2007.
  32. “Recent advances in polymer shape memory,” Polymer, vol. 52, no. 22, pp. 4985–5000, 2011.
  33. “Mechanics of networked proteins and cells,” Current Opinion in Cell Biology, vol. 32, pp. 72–79, 2015.
  34. “Chemical Engineering Process Simulation,” in Transport Phenomena and Unit Operations, 3rd ed., Wiley, 2013.
  35. “Multi-responsive polymers,” in Smart Polymers and Their Applications, Woodhead Publishing, 2014, pp. 201–230.
  36. “Polyactic acid (PLA) matrices for orthopedic regeneration,” in Handbook of Composites: From Aerospace to Energy and Infrastructure, Springer, 2011, pp. 421–433.
  37. “Self-assembling nanoparticles for therapeutics and diagnostics,” Progress in Polymer Science, vol. 36, no. 10, pp. 1294–1326, 2011.
  38. “Biomimetics: Nature-based innovation,” CRC Press, 2010.
  39. “Multi-responsive polymers for smart drug delivery,” Journal of Controlled Release, vol. 190, pp. 15–28, 2014.
  40. “3D printing polymer nanocomposites: Techniques and applications,” in 3D Printing Technology and Its Applications, Springer, 2019, pp. 237–268.
  41. “Review of shape memory polymers and their applications in additive manufacturing,” Journal of Applied Materials, vol. 8, no. 4, pp. 456–478, 2018.
  42. “Computational polymer science,” Chemistry Today, vol. 25, no. 1, pp. 20–29, 2007.
  43. “Shape-memory properties of polypropylene,” Progress in Polymer Science, vol. 37, no. 3, pp. 417–440, 2012.
  44. “Cyclic deformation behavior of elastomers at low temperatures,” Polymer, vol. 51, no. 24, pp. 5769–5776, 2010.
  45. “Mechanical properties of thermoplastic elastomers at extreme temperatures,” Journal of Materials Science, vol. 45, no. 19, pp. 5291–5304, 2010.
  46. “Deformation and Fracture Mechanics of Engineering Materials,” 5th ed., Wiley, 2012.
  47. “Developments in construction-scale additive manufacturing processes,” Automation in Construction, vol. 21, pp. 262–268, 2012.
  48. “Additive manufacturing of tissues and organs,” Progress in Polymer Science, vol. 37, no. 8, pp. 1079–1104, 2012.
  49. “Material characterization and compressive strength of fused deposition modeling (FDM) thermoplastics,” in Proceedings of the Rapid Prototyping & Manufacturing Conference, 2008, pp. 1–8.
  50. “Parametric appraisal of mechanical property of fused deposition modelling processed parts,” Journal of Materials Processing Technology, vol. 208, no. 1–3, pp. 330–339, 2008.
  51. “Selective laser sintering of polycarbonate and polyetheretherketone,” in Solid Freeform Fabrication Proceedings, 1992, pp. 1–8.
  52. “Shape memory materials for minimally invasive surgery: a review,” in Materials for Biomedical Devices, Woodhead Publishing, 2010, pp. 152–186.
  53. “3D Printing and Additive Manufacturing: Principles and Applications,” 5th ed., World Scientific Publishing, 2017.
  54. “Progress in additive manufacturing and rapid prototyping,” CIRP Annals – Manufacturing Technology, vol. 57, no. 2, pp. 733–759, 2008.
  55. “Improving dimensional accuracy of fused deposition modeling processed part using grey Taguchi method,” Materials & Design, vol. 30, no. 10, pp. 4243–4252, 2009.
  56. “Taguchi Techniques for Quality Engineering: Loss Function, Orthogonal Experiments, Parameter and Tolerance Design,” 2nd ed., McGraw-Hill, 1996.
  57. “Processing and characterization of a new calcium fluoride reinforced composite,” Materials Science and Engineering A, vol. 409, no. 1–2, pp. 220–228, 2005.
  58. “Optimization of rapid prototyping process using Design of Experiments,” Advanced Materials Research, vol. 265–270, pp. 1–12, 2011.
  59. “Assessing design and manufacturing parameters of fused deposition modeling process,” Materials Today: Proceedings, vol. 5, no. 5, pp. 11667–11673, 2018.
  60. “Physical and mechanical properties of polylactic acid plastic,” in Biomedical Applications of Biopolymers, Woodhead Publishing, 2013, pp. 45–67.
  61. “Optimization of rapid prototyping process using Design of Experiments,” Advanced Materials Research, vol. 265–270, pp. 1–10, 2011.
  62. “Handbook of Elastomers: New Developments and Technology,” 2nd ed., ChemTech Publishing, 2012.
  63. “Thermomechanical characterization of composite materials fabricated through 3D printing,” Composites Part B: Engineering, vol. 110, pp. 109–117, 2017.
  64. “Computational analysis of extrusion processes for additive manufacturing,” in Proceedings of the ASME 2018 International Design Engineering Technical Conferences, 2018.
  65. “Anisotropic behavior of fused deposition modeling parts obtained by different internal structures,” Journal of Engineering Materials and Technology, vol. 140, no. 1, article 011003, 2018.
  66. “Computational analysis of thermal properties in FDM printing,” in Advanced Manufacturing and Fabrication, Springer, 2016, pp. 234–256.
  67. “Characterization of mechanical properties in layered composites,” Journal of Composite Materials, vol. 51, no. 15, pp. 2115–2128, 2017.
  68. “Honeycomb structures in additive manufacturing,” Journal of Materials Engineering and Performance, vol. 26, no. 6, pp. 2847–2859, 2017.
  69. “Shape memory effects in thermoplastics,” Advanced Engineering Materials, vol. 19, no. 8, article 1700117, 2017.
  70. “Recovery forces in shape memory polymer composites,” Polymers, vol. 9, no. 12, article 631, 2017.
  71. “Stereolithography for shape memory polymer fabrication,” Macromolecular Materials and Engineering, vol. 302, no. 12, article 1700256, 2017.
  72. “Microstructure and cyclic degradation in SMPs,” Polymer, vol. 98, pp. 392–403, 2016.
  73. “Fatigue behavior of shape memory polymers under cyclic loading,” Composites Part B: Engineering, vol. 107, pp. 47–58, 2016.
  74. “Medical device design using 4D printing,” Advanced Healthcare Materials, vol. 6, no. 12, article 1700217, 2017.
  75. “Soft robotic actuators and their cyclic performance,” Soft Matter, vol. 13, no. 26, pp. 4681–4694, 2017.
  76. “Build orientation effects on cyclic properties of FDM parts,” Rapid Prototyping Journal, vol. 23, no. 5, pp. 966–976, 2017.
  77. “Material selection strategies for 3D printing,” Progress in Materials Science, vol. 65, pp. 29–120, 2014.
  78. “A practical guide to additive manufacturing materials,” Journal of Materials Processing Technology, vol. 229, pp. 469–487, 2016.
  79. “Economic analysis of 4D printing technology,” International Journal of Advanced Manufacturing Technology, vol. 95, no. 5–8, pp. 3349–3361, 2018.
  80. “Prosthetic design using shape memory polymers,” Biomaterials, vol. 32, no. 26, pp. 6034–6047, 2011.
  81. S. Tibbits, “4D printing: Multi-material shape change,” Architectural Design, vol. 84, no. 1, pp. 116–121, 2014.